Why Larger Pores in SOLESPHERE™ Silica Solid Sorbents Improve CO₂ Capture Efficiency

solid sorbent for CO₂ Capture

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Carbon capture technologies play a critical role in mitigating climate change by removing carbon dioxide (CO₂) from industrial emissions and the atmosphere. According to the International Energy Agency, carbon capture systems could eliminate up to 20% of greenhouse gas emissions by 2050.

Despite their environmental benefits, carbon capture systems are often energy intensive. They consume large amounts of energy, which increases operational costs and contributes to emissions. However, advanced materials can improve CO₂ adsorption rates, helping reduce energy demand, operating costs, and the environmental impact of carbon capture systems.

For carbon capture technology firms looking to improve efficiency, independent testing demonstrates a clear material advantage for mesoporous silica solid sorbents. According to tests conducted by the University of Cincinnati, solid sorbents with larger pores, like RESIFA™ SOLESPHERE™ silica, deliver stronger adsorption performance than competing materials. Large pore volumes and pore diameters support higher amine loading, which improves CO₂ capture efficiency while reducing regeneration energy demand and operating costs.

What Are Amine-Treated Mesoporous Silicas?

Mesoporous silicas, such as SOLESPHERE grades, are highly effective solid sorbent materials for CO₂ capture. Amine-treated silica particles provide high CO₂ adsorption capacity, helping improve carbon capture efficiency across industrial and direct air capture applications. These silica grades also demonstrate excellent thermal and mechanical stability.

How Porous SOLESPHERE Silica Improves CO Capture

Pore structure and pore volume significantly affect the performance of solid sorbents used in carbon capture systems. Recent thermogravimetric analysis conducted by Dr. Joo-Youp Lee at the University of Cincinnati shows that SOLESPHERE grades deliver strong adsorption performance for better carbon capture efficiency. The combination of porosity, pore volume and pore diameter supports several advantages in carbon capture applications.

Higher Amine Loading Capacity

SOLESPHERE microspherical silica is engineered for high-performance amine loading in CO₂ capture applications. Its optimized particle size and porosity, along with a large pore volume andstructure, provide an excellent foundation for amine treatments

Stability and Compatibility with Amine

(Tested with University of Cincinnati original amine)

SOLESPHERE solid sorbent for carbon capture

Increased Adsorption Rate

The porous structure of SOLESPHERE silica supports  CO₂ adsorption capacity. Amine-treated SOLESPHERE silica can adsorb more CO₂ than competing silicas, especially at low concentrations (e.g., 400ppm ). Using the same amine, SOLESPHERE silica improved the adsorption performance by 25% compared to the benchmark silica, which was originally designed for this application.

Comparison of Silica Supports for COAdsorption

(Test results from the University of Cincinnati using the same amine)

Comparison of Silica Supports for CO₂ Adsorption

Better System Efficiency

Carbon capture systems require significant energy to remove CO₂ from industrial emissions and ambient air. Porous solid sorbents can improve the efficiency of these systems, such as SOLESPHERE silica. SOLESPHERE grades contribute to higher CO₂ adsorption capacity and require fewer carbon capture cycles, helping reduce energy consumption and operating costs.

Select the Best SOLESPHERE Silica Grade for Your Carbon Capture Application

AGC Chemicals Americas offers a variety of RESIFA SOLESPHERE silica grades with large pores for carbon capture. It is available in three forms: bare silica, silica pellets and amine-treated silica pellets, in a range of particle sizes, surface areas, pore volumes and pore diameters to fit different applications. 

  • SOLESPHERE DM-L-303: Features the largest particle size and highest pore volume and pore diameter for maximum amine loading capacity and high CO₂ adsorption performance.
  • SOLESPHERE L-123: Combines a smaller particle size with high pore volume and large pore diameter for balanced adsorption performance and efficient gas diffusion
  • SOLESPHERE H-53: Small particle size and diameter with the largest  surface area and high  pore volume ideal for certain functionalization methods.

Ready to improve your carbon capture efficiency with advanced mesoporous silica solid sorbents? Download this brochure to learn more about advanced SOLESPHERE grades.